MoS2-Ti composite coatings were deposited by pulsed magnetron sputtering system on silicon wafers and aluminium bronze (C63200) substrates. Ti content was controlled by different current applied on Ti target. Morphology, composition, tribological properties and structure were respectively investigated by SEM, EDS, ball on disk tribometer and XRD. Results show that with increasing of Ti from 0% to 23%, the compactness of coatings increased gradually and structure were changed from high crystallinity of dominant orientation on basal panels (002) to amorphous forms. Friction and wear test showed that with increasing of Ti fraction, tribological properties were improved firstly and then degraded, 3%Ti coating has friction coefficient as low as 0.015 at room temperature in vacuum, while 23%Ti coating showed no lubrication. As elevated temperature to 400°C, higher friction coefficient and wider wear scar were brought about, even friction coefficient were increased from 0.015~0.04 to 0.07~0.1, 13%Ti coating damaged after 800s at 400°C in wear test. Wear debris and particles were observed on the friction pairs of pure MoS2 and 13%Ti coating at 400°C.