Based on the Mie’s scattering theory, the light scattering characteristic of Al2O3 tail plume plasma for a spacecraft was studied. Influences of the complex refractive index onthe extinction efficiency factor, scattering efficiency factor, absorb efficiency factor, scattering phase function and the single-scattering albedo of an Al2O3 particle were analyzed by using the Mie’s scattering theory. Meanwhile, based on the particle scale unimodal distribution with a polydispersity, the changes of the concerned effect factors and the scattering phase function were analyzed with considering the Al2O3particle size, and some numerical simulations were also given. The theoretical and numerical simulation studies show that the imaginary and real part of the refractive index of the Al2O3 particles, the radius and its distribution of the particles bring out great effect on the scattering phase function, extinction and scattering efficiency factors and single-scattering albedo.