Polymers are prepared under methane plasma environment, and appear to be white, slightly yellow, soft thread-like powders and floc under optical microscope. The polymers contain –CH3, -CH2, C-O, -C=C-, -OH etc. functional groups, but no simplex carbons. It is found that the solubility of this polymer is less than 0.1mg.ml-1 in different organic solvent. The productivity of the polymers is higher under a plasma environment with higher ionization, higher polarization of neutral gas, lower environment temperature and less permittivity.