This paper presents PIC/MC model of capacitively coupled very-high-frequency discharge in hydrogen. We take into account 21 kinds of collisions of charged particles (e, H+,H2+, H3+) with H2, have simulated the electric field distribution, potential distribution, density and mean energy distribution of electrons and hydrogen ions ( H+, H2+, H3+), and have compared with those of the frequency of 13.56MHz. The simulation results show that the plasma space potential is enhanced with the increase of driving frequency, which results in the increase of electric field near the two electrodes. Besides, rf sheath thickness becomes thin and the mean energy of electron and H3+ is decreased, while their total density is increased with the increase of frequency. H3+ is the dominant ion in the H2 very-high-frequency discharge, its density being two or three orders of magnitude higher than that of H2+.