面向等离子体ODS-W复合材料的制备工艺

核聚变与等离子体物理 ›› 2014, Vol. 34 ›› Issue (4): 348-354.

面向等离子体ODS-W复合材料的制备工艺

张俊，朱晓勇，罗来马，罗广南，程继贵，吴玉程

(1. 合肥工业大学材料科学与工程学院，合肥230009； 2. 安徽省有色金属材料与加工工程实验室，合肥230009； 3. 中国科学院等离子体物理研究所，合肥230031)

收稿日期:2014-01-23 修回日期:2014-07-23 出版日期:2014-12-15 发布日期:2014-12-15
作者简介:张俊(1990-)，男，湖北黄冈人，硕士研究生，主要从事有色金属与粉末冶金研究。
基金资助:
国家磁约束核聚变能发展研究专项(2014GB121001, 2010GB109004)；国家自然科学基金资助项目(51204064)

Preparation technology of plasma facing ODS-W composites

ZHANG Jun,, ZHU Xiao-yong , LUO Lai-ma,LUO Guang-nan , CHENG Ji-gui, WU Yu-cheng

(1. School materials Science and Engineering, Hefei University of Technology, Hefei 230009; 2. Laboratories of nonferrous metal material and processing engineering of Anhui province, Hefei 230009； 3. Institute of Plasma Physics, Chinese Academic Sciences, Hefei 230031)

Received:2014-01-23 Revised:2014-07-23 Online:2014-12-15 Published:2014-12-15

摘要/Abstract

摘要：

向钨中添加稀土氧化物能显著细化晶粒和提高钨合金的高温稳定性，且具有弥散强化效应，在抑制晶粒长大、控制再结晶晶粒的形状以及提高材料的力学性能方面效果显著。从制备稀土氧化物弥散强化钨基复合材料(ODS-W)粒子方法出发，阐述了几种ODS-W制备工艺的研究现状并对其发展趋势进行展望。

关键词: 面向等离子体材料, 稀土氧化物, 钨基复合材料, 制备技术

Abstract:

Addition of rare earth oxide to the tungsten can significantly refine the grain and improve high temperature stability of the tungsten alloys, which also have the dispersion strengthening effect and significant effect in the suppression of grain growth, controllingthe re-crystallization grain shape and improving the mechanical properties of the materials. This paper expounds current situation of several techniques of preparing ODS-W from the perspective of preparation method of ODS-W particles and forecasts its development trend.

Key words: Plasma facing materials, Rare earth oxides, Tungsten matrix composites, Preparation technology

中图分类号:

TG146.1

张俊，朱晓勇，罗来马，罗广南，程继贵，吴玉程. 面向等离子体ODS-W复合材料的制备工艺[J]. 核聚变与等离子体物理, 2014, 34(4): 348-354.

ZHANG Jun,ZHU Xiao-yong , LUO Lai-ma,LUO Guang-nan , CHENG Ji-gui, WU Yu-cheng. Preparation technology of plasma facing ODS-W composites[J]. NUCLEAR FUSION AND PLASMA PHYSICS, 2014, 34(4): 348-354.

参考文献

[1] 周张健, 钟志宏, 沈卫平. 聚变堆中面向等离子体材料的研究进展[J]. 材料导报, 2005, 19(12): 5−8.
[2] 万元熙. 磁约束核聚变研究现状和前景展望[J]. 现代物理知识, 1999, 11(5): 17−19.
[3] 邱励俭. 核聚变研究50 年[J]. 核科学与工程, 2001, 21(1): 29−38.
[4] 刘丹华, 谌继明, 吴继红, 等. 国际热核实验堆第一壁材料CuCrZr合金及其与不锈钢焊接接头的力学性能[J]. 机械工程材料, 2009, 33(3): 46−49.
[5] Takeshi Hirai, Koichiro Ezato, Patrick Majerus. ITER relevant high heat flux testing on plasma facing surfaces[J]. Materials Transactions, 2005, 46(3): 412−424.
[6] 丁亚清. 国际热核实验反应堆(ITER)真空室的设计介绍[J]. 真空与低温, 2005, 11(3): 182−186.
[7] Andreni R. The European technology fusion programme[J]. Fusion Engineering and Design, 2001, 56−57: 5−18.
[8] 许增裕. 聚变材料研究的现状和展望[J]. 原子能科学技术, 2003, 37(S1): 105−110.
[9] 种法力, 陈俊凌, 李建刚. Tokamak 第一壁上W/Cu材料的连接和界面应力的研究[J]. 稀有金属与硬质合金, 2005, 33(4): 38−41.
[10] Barabash V, Akiba M, Mazul I, et al. Selection, development and characterisation of plasma facing materials for ITER [J]. J. Nucl. Mater., 1996, 233−237(1): 718−723.
[11] Tanabe T, Wada M, Ohgo T, etal. Application of tungsten for plasma limiters in TEXTOR [J]. J. Nucl. Mater., 2000, 283−387: 1128−1133.
[12] Yuji Kitsunai, Hiroaki Kurishita, Hideo Kayano, et al. Microstructure and impact properties of ultra-fine grained tungsten alloys dispersed withTiC [J]. J. Nucl. Mater., 1999, 271−272: 423−428.
[13] Michael Rieth, Bernhard Dafferner. Limitations of W and W-1%La2O3 for use as structural materials [J]. J. Nucl. Mater., 2005, 342(1−3): 20−25.
[14] Hong S H, Kang S L, Yoon D N, et al. The reduction of the interfacial segregation of phosphorus and its embrittlement effect by lanthanum addition in a W-Ni-Fe heavy alloy [J]. Metallurgical Transaction A, 1991, 22(12): 2969−2974.
[15] Wu G C, You Q, Wang D. Influence of the addition of Lanthanum on a W-Mo-Ni-Fe heavy alloy [J]. International Journal of Refractory Metals and Hard Materials, 1999, 17(4): 299−304.
[16] Muñoz A, Monge M A,Savoini B, et al La2O3 reinforced W and W-V alloys produced by hot isostatic pressing [J]. J. Nucl. Mater., 2011, 417(1−3): 508?511.
[17] Wesemann I, Spielmann W, Heel P, et al. Fracture strength and microstructure ofODS tungsten alloys [J]. International Journal of Refractory Metals and Hard Materials, 2010, 28(6): 687–691.
[18] Youngmoo Kim, Moon-Hee Hong,Sung Ho Lee, et al.The effect of yttrium oxide on the sintering behavior and hardness of tungsten [J].Metals and Materials International, 2006, 12(3): 245−248.
[19] Aguirre M V, Martín A, Pastor J Y, et al. Mechanical properties of Y2O3-doped W-Ti alloys [J]. J. Nucl. Mater., 2010, 404(3): 203–209.
[20] Muñoz A, Martínez J, Monge M A, et al. SANS evidence for the dispersion of nanoparticles in W-1Y2O3 and W-1La2O3 processed by hot isostatic pressing [J]. International Journal of Refractory Metals and Hard Materials, 2012, 33: 6−9.
[21] Cui K, Shen Y Z, Yu J, et al. Microstructural characteristics of commercial purity W and W-1% La2O3 alloy [J]. International Journal of Refractory Metals and Hard Materials, 2013, 41: 143–151.
[22] Aguirre M V, Martín A, Pastor J Y, et al. Mechanical properties of tungsten alloys with Y2O3 and titanium additions [J]. J. Nucl. Mater., 2011, 417(1−3): 516−519.
[23] Lee K H, Cha S I, Ryu H J, et al. Effect of two-stage sintering process on microstructure and mechanical properties of ODS tungsten heavy alloy [J]. Materials Science and Engineering A, 2007, 458(1−2): 323–329.
[24] Park S, Kim D K, Lee S , et al. Dynamic deformation behavior of an oxide-dispersed tungsten heavy alloy fabricated by mechanical alloying [J]. Metallurgical and Materials Transactions A, 2001, 32(8): 2011−2020.
[25] Ryu H J, Hong S H. Fabrication and properties of mechanically alloyed oxide-dispersed tungsten heavy alloys [J]. Materials Science and Engineering A, 2003, 363(1−2): 179−184.
[26] 陈勇, 吴玉程, 于福文, 等. 机械合金化制备TiC/W纳米晶复合粉体的烧结特性[J]. 稀有金属材料与工程, 2007, 36(5): 822−824.
[27] 种法力, 陈勇, 吴玉程, 等. La2O3弥散增强钨合金面对等离子体材料及其高热负荷性能[J]. 材料科学与工程学报, 2009, 27(3): 415−417.
[28] Veleva L, Oksiuta Z, VogtU, et al. Sintering and characterization of W-Y and W-Y2O3 materials [J]. Fusion Engineering and Design, 2009, 84(7−11): 1920–1924.
[29] Zhangjian Zhou, Jun Tan, Dandan Qu, et al. Basic characterization of oxidedispersion strengthened fine-grained tungsten based materials fabricated by mechanical alloying and spark plasma sintering [J]. J.Nucl. Mater., 2012, 431(1−3): 202−205.
[30] Chen C L, Huang C L. The effects of alloying and milling on the formation of intermetallics in ODS tungsten heavy alloys [J]. Intermetallics, 2013, 41: 10−15.
[31] Savoini B, Martínez J, Muñoz A, et al. Microstructure and temperature dependence of the microhardness of W-4V-1La2O3and W-4Ti-1La2O3[J]. J. Nucl. Mater., 2013, 442(1−3): S229–S232.
[32] Palacios T, Pastor J Y,Aguirre M V, et al. Mechanical behavior of tungsten-vanadium-lanthana alloys as function of temperature [J]. J. Nucl. Mater., 2013, 442(1−3): S277–S281.
[33] Kim Y, Lee K H, Kim E, et al. Fabrication of high temperature oxides dispersion strengthened tungsten composites by spark plasma sintering process [J]. International Journal of Refractory Metals and Hard Materials, 2009, 27(5): 842–846.
[34] Zhuge F, Ye Z Z, Wang F Z, et al. Nanocomposite W-4.5%ThO2 thermionic cathode [J]. Materials Letters, 2003, 57(19): 2776−2779.
[35] Liu R, Wang X P, Hao T, et al. Characterization of ODS-tungsten microwave-sintered from sol-gel prepared nano-powders [J]. J. Nucl. Mater., 2014, 450(1−3): 69−74.
[36] Liu R, Zhou Y, Hao T, et al. Microwave synthesis and properties of fine-grained oxides dispersion strengthened tungsten [J]. J. Nucl. Mater., 2012, 424(1−3): 171–175.
[37] Xu L, Yan Q Z , Xia M, et al. Preparation of La2O3 doped ultra-fine W powders by hydrothermal-hydrogen reduction process [J]. International Journal of Refractory Metals and Hard Materials, 2013, 36: 238−242.
[38] Mazher Ahmed Yar, Sverker Wahlberg, Hans Bergqvist, et al. Chemically produced nanostructured ODS- lanthanum oxide-tungsten composites sintered by spark plasma [J]. J. Nucl. Mater., 2011, 408(2): 129-135.
[39] Yar M A, Sverker Wahlberg, Hans Bergqvist, et al. Spark plasma sintering of tungsten-yttrium oxide composites from chemically synthesized nanopowders and microstructural characterization [J]. J. Nucl. Mater., 2011, 412(2): 227−232.
[40] Sverker Wahlberg, Mazher A Yar, Mohammad Omar Abuelnaga, et al. Fabrication of nanostructured W-Y2O3 materials by chemical methods[J]. Journal of Materials Chemistry, 2012, 22: 12622−12628.
[41] Xia M, Yan Q Z, Xu L, et al. Bulk tungsten with uniformly dispersed La2O3 nanoparticles sintered from co-precipitated La2O3/W nanoparticles [J]. J. Nucl. Mater., 2013, 434(1−3): 85−89.