介质阻挡放电等离子体与重油反应的研究

核聚变与等离子体物理 ›› 2012, Vol. 32 ›› Issue (3): 271-277.

介质阻挡放电等离子体与重油反应的研究

于红1，凌伟1，赵明2，王杰祥2，刘彦民1

(1. 中国石油大学华东理学院，青岛 266555；2. 中国石油大学华东石油工程学院，青岛 266555)

收稿日期:2011-11-30 修回日期:2012-05-03 出版日期:2012-09-15 发布日期:2012-09-14
作者简介:于红(1977-)，女，山东烟台人，博士，副教授，从事低温等离子体应用研究。
基金资助:
国家自然科学基金大气压非平衡等离子体降粘超稠油的基础研究(20706060)；中国石油天然气集团公司中青年创新基金超稠油冷等离子体降粘的基础研究(07E1022)；高等学校博士学科点专项科研基金超稠油的非平衡等离子体降粘机理研究(20070425515)；山东省自然科学基金超稠油的大气压冷等离子体降粘机制研究(Q2007B06)

Reaction of dielectric barrier discharge plasma with crude oil

YU Hong1, LING Wei1, ZHAO Ming2, WANG Jie-xiang2, LIU Yan-min1

(1. College of Physics Science and Technology in China University of Petroleum, Qingdao 266555; 2. School of Petroleum Engineering in China University of Petroleum, Qingdao 266555)

Received:2011-11-30 Revised:2012-05-03 Online:2012-09-15 Published:2012-09-14

摘要/Abstract

摘要：

分别采用空气、氩气大气压介质阻挡放电(DBD)等离子体对重油进行了处理。对经空气DBD等离子体处理后的重油进行粘温特性分析，发现重油粘度升高，流动性变差。红外光谱和四组分分析结果表明重油的重质组分含量升高，重油胶体体系被破坏，同时生成大量刺激性气味气体。为了便于分析气态产物的成分和含量，采用大气压氩气DBD等离子体处理重油并收集气体产物。气相色谱分析发现生成气中含有大量C₁-C₅的烃类和一定量氢气，其中氢气和甲烷含量占生成气的70%以上。实验结果表明重油在等离子体作用下既发生裂解又发生聚合反应，既生成低碳烃类，本身的流动性也变差。

关键词: 介质阻挡放电, 空气, 氩气, 重油

Abstract:

Heavy oil was treated in dielectric barrier discharge (DBD) plasma reactor with air and argon used as the work gas respectively. When air was used, the oil became more viscous. Results from Fourier transform infrared spectroscopy measurement and the SARA analysis showed that the oil colloidal system was destroyed, a lot of gas was produced, and heavier components (Resin and asphaltene) left in oil. To make the analysis and explanation easier, argon was used as work gas. Gas chromatography (FID and TCD) was used to analyze the gas production, there were lot of C₁−C₅ hydrocarbons, and H2 was also of great concentration. Total content of hydrogen and methane is more than 70% of gaseous product. This showed that the cracking of heavy oil occurred. Heavy oil mobility was deteriorated by plasma, this indicated that polymerization reaction occurred as well as heavy oil was cracked.

Key words: Dielectric barrier discharge plasma, Air, Argon, Heavy oil

中图分类号:

O539

于红1，凌伟1，赵明2，王杰祥2，刘彦民1. 介质阻挡放电等离子体与重油反应的研究[J]. 核聚变与等离子体物理, 2012, 32(3): 271-277.

YU Hong, LING Wei, ZHAO Ming, WANG Jie-xiang, LIU Yan-min. Reaction of dielectric barrier discharge plasma with crude oil[J]. NUCLEAR FUSION AND PLASMA PHYSICS, 2012, 32(3): 271-277.

参考文献

[1] 徐学基, 诸定昌. 气体放电物理学[M]. 上海: 复旦大学出版社, 1996.

[2] 朱承驻, 董文博, 潘循皙, 等. 等离子体降解水相中有机污染物的机理研究[J]. 环境科学学报, 2002, 22(4): 428-433.

[3] 詹花茂, 李成榕, 许金豹, 等. 用于材料表面处理的空气中的均匀DBD[J]. 高电压技术, 2008, 34(3): 508-511.

[4] 邹吉军, 李阳, 张月萍, 等. 甲烷二氧化碳DBD转化产物分布研究[J]. 物理化学学报, 2002, 18(8): 759-763.

[5] Prieto G, Okumoto M, Takashima K, et al. Reforming of heavy oil using nonthermal plasma[J]. IEEE Transactions on Industry Applications, 2001, 37(5): 1464 -1467.

[6] Prieto G, Okumoto M, Shimano K, et al. Heavy oil conversion by plasma chemical reactors[A]. IEEE Conference Publications, 1999, 2: 1144-1149.

[7] Prieto G, Okumoto .M, Takashima K, et al. A plate-to-plate plasma reactor as a fuel process for hydrogen-rich gas production[A]. IEEE Conference Publications, 2001, 2: 1099-1102.

[8] Kong C P, Nelson O L, Detering A B. Nonthermal plasma systems and methods for natural gas and heavy hydrocarbon co-conversion[P]. US Patent: 6986854 B2, 2005-5-24.

[9] Kong C P, Nelson O L, Detering A B. Methods for natural gas and heavy hydrocarbon co-conversion[P]. US Patent: 7494574 B2, 2009-2-24.

[10] 程月. 空气低温氧化原油组成和气体组成变化规律研究[D]. 哈尔滨: 哈尔滨工程大学, 2007.

[11] 王杰祥, 张琪, 李爱山, 等. 注空气驱油室内实验研究[J]. 石油大学学报(自然科学版), 2003, 27(4): 73-75.

[12] 寇建益. 温度变化对原油低温氧化过程影响研究[D].北京: 中国科学院研究生院(理化技术研究所), 2008.

[13] 张怀平, 吕春祥, 李开喜, 等. 煤焦油与石油渣油空气氧化的比较研究[J]. 煤炭转化, 2001, 24(3): 79-82.

[14] 张怀平, 吕春祥, 李开喜, 等. 石油渣油空气氧化和氮气热缩聚的比较研究[J]. 石油炼制与化工, 2002, 33(1): 42-46.

[15] 杨恩翠, 郝金库, 王保伟, 等. 甲烷等离子体偶联合成碳二烃反应过渡态和反应途径的理论研究[J]. 天津师范大学学报(自然科学版), 2002, 22(1): 1-5.

[16] 高爱华, 苏斌, 井波, 等. 甲烷在直流放电等离子体中形成自由基研究[J]. 西安石油大学学报(自然科学版), 2010, 25(1): 68-76.